Harnessing Zn-Volatility for Compositional Tuning in PtZn Nanoalloy Catalysts

Bimetallic nanoalloys have gained extensive attention due to their tunable properties and wide range of catalytic applications. However, achieving good compositional control in nanoalloy catalysts remains a formidable challenge. In this work, we demonstrate that heat treatment can be used to tune the composition of Pt-Zn nanoalloy catalysts, leveraging the volatile nature of zinc to enhance their performance in propane dehydrogenation. Through identical location (scanning) transmission electron microscopy (IL-(S)TEM) using an in-situ EM gas cell, as well as other complementary techniques, we observed that the zinc content of the Pt-Zn nanoalloy particles decreased over time of the heat treatment under hydrogen. The rate of change depends on the original composition of the particles, as well as the heat treatment conditions such as temperature and flow rate. Our experimental results and theoretical calculations suggest that Zn in the intermetallic phase might be more stable, providing an opportunity for precise tuning the nanoparticle compositions. This approach presents a viable strategy for developing better Pt-Zn catalysts for propane dehydrogenation.