A Decade of Progress: Review of the Synthesis of Dibenzo[b,f]oxepines

This review article highlights the significant advances in the synthesis of dibenzo[ b , f ]oxepines over the past decade. Dibenzo[ b , f ]oxepines, important heterocyclic compounds, have attracted increasing interest due to their wide‐ranging applications in medicinal chemistry and materials applications. The review addresses traditional approaches and recent developments, highlighting efficient synthetic strategies such as cross‐coupling reactions, intramolecular cyclizations, and molecular diversification strategies. Additionally, the efficiency, selectivity, and sustainability of these methods are discussed. Emerging trends and future challenges in the synthesis of dibenzo[ b , f ]oxepines are also explored, including the search for more sustainable methods, the expansion of structural diversity, and the optimizing reaction conditions. This review provides a comprehensive overview of recent advances in this field, providing valuable insights for researchers aiming to develop novel synthetic strategies and applications for dibenzo[ b , f ]oxepines.