Visible-to-near-infrared light-harvesting A-π-D-π-A porphyrins for boosted photocatalytic hydrogen evolution

Visible-to-near-infrared light-harvesting A-π-D-π-A porphyrins, ZnP-CPDT and ZnP-BT are proved to be highly efficient in photocatalytic hydrogen evolution (PHE) with the highest PHE rate ( η H 2 ) of 1.80 mmol g −1 h −1 for ZnP-CPDT.