铱
对映选择合成
化学
催化作用
不对称氢化
有机化学
催化加氢
Noyori不对称加氢
组合化学
作者
Bram B. C. Peters,Norman Birke,Pher G. Andersson,Luca Massaro
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2022-12-22
卷期号:34 (12): 1519-1523
被引量:1
标识
DOI:10.1055/s-0042-1751399
摘要
Abstract The catalytic asymmetric hydrogenation of olefins constitutes a powerful method for the preparation of chiral compounds. A series of prochiral unsaturated amides were efficiently reduced with high enantioselectivities by means of an iridium N,P-complex-catalyzed hydrogenation. Its application in the synthesis of fenpropidin and the possibility of using isomeric mixtures of starting materials are attractive features of the method.
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