化学
功能群
光催化
自由基环化
药物化学
酰基
光化学
组合化学
有机化学
群(周期表)
催化作用
光催化
聚合物
作者
Pengfei Huang,Jia-Le Fu,Jia-Jing Huang,Biquan Xiong,Kewen Tang,Yu Lan
摘要
We herein report an efficient photoredox radical cyclization reaction of o-vinylaryl isocyanides with acyl chlorides to access a wide range of 2,4-disubstituted quinolines. Preliminary mechanism experiment results suggested that this reaction was initiated by an acyl radical generated from acyl chlorides through a single-electron-transfer (SET) process. This transformation showed good substrate suitability and functional group compatibility at room temperature.
科研通智能强力驱动
Strongly Powered by AbleSci AI