荧光粉
温度计
激发态
发光
兴奋剂
材料科学
猝灭(荧光)
光电子学
分析化学(期刊)
大气温度范围
激发
荧光
化学
光学
原子物理学
电气工程
物理
气象学
工程类
量子力学
色谱法
作者
Zhen Sun,Zuoling Fu,Liang Ma,Hongwen Cao,Mingli Wang,Huiju Cao,Anqi Zhang
标识
DOI:10.1016/j.apsusc.2021.151791
摘要
To meet the demand of ultra-sensitive and high accurate temperature measurements especially in the fields of medical treatment and diagnosis, multi-mode FIR-based optical thermometers as a novel strategy have been developed in recent years. In this work, two types of temperature probes, CaNb2O6 (CNO): Tb3+, Eu3+ and CNO: Tb3+, Sm3+, are firstly designed by high-temperature solid-state method. CNO possesses bright cyan emission excited at 267 nm, wide band gap and good temperature sensing property relative to BaNb2O6 (BNO) and SrNb2O6 (SNO) materials due to sandwich-type structure. Upon 267 nm excitation, Tb3+–Eu3+/Sm3+ doped CNO phosphors achieve multi-color tuning by host → Tb3+→Eu3+/Sm3+ ET channels. Furthermore, the characteristic emission intensity of Tb3+ decrease quickly than that of Eu3+ and Sm3+ due to the competition between thermal quenching and ET process as temperature rising. In the view of different temperature-dependent behaviors, multi-mode FIR (FIR1: ITb1/IEu1/Sm1, FIR2: ITb2/IEu2/Sm2, FIR3: ITb1/IEu2/Sm2 and FIR4: ITb2/IEu1/Sm1) show excellent temperature-sensing performance with the maximum Sa and Sr of 0.036 K−1/ 4.09 % K−1 at high temperature. This work provides a new luminescent material to gain excellent optical thermometer with low cost and high accuracy by multi-mode FIR collaboration.
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