DPPH
抗氧化剂
食用菌
内翻性腭裂
化学
蘑菇
保健品
圆二色性
有机化学
立体化学
生物化学
食品科学
生物
细菌
遗传学
菌根
共生
作者
Jing Lv,Lan Yao,Jinxiu Zhang,Lian Wang,Jun Zhang,Ying‐Ping Wang,Xiao Shuhua,Changtian Li,Liang Yu
标识
DOI:10.1021/acs.jafc.1c01160
摘要
Wild edible mushrooms are important as a source of nutraceuticals and for the discovery of bioactive metabolites as pharmaceuticals. In this work, 10 rare 2,5-diarylcyclopentenone derivatives were isolated from the wild edible mushroom Paxillus involutus (Batsch) Fr., including eight novel compounds termed involutenone A–H (1–8) and two previously identified compounds (9–10). Their structures were established using high-resolution electrospray ionization mass spectroscopy and 1D and 2D nuclear magnetic resonance data. The absolute configurations of compounds 1–3 and 6–8 were assigned based on the comparison of the experimental and calculated electronic circular dichroism data. The antioxidant activities of 1–8 were tested through DPPH free radical scavenging, hydroxyl radical scavenging, and superoxide anion radical scavenging assays. Compounds 3, 5, 6, and 7 demonstrated significant antioxidant activity compared to the positive control (tert-butylhydroquinone). These compounds could be effective natural antioxidants with considerable pharmaceutical value.
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