材料科学
阴极
电化学
电极
共轭体系
离子
化学工程
离子键合
聚合
混合材料
纳米技术
聚合物
复合材料
有机化学
物理化学
化学
工程类
作者
Yijun Gao,Ping Xue,Lijun Ji,Xin Pan,Lining Chen,Wei Guo,Mi Tang,Chengliang Wang,Zhengbang Wang
标识
DOI:10.1021/acsami.1c23840
摘要
Conjugated quinones are promising cathode materials for sodium-ion batteries. However, the contemporary primary conjugated quinones cathodes still hold to limited capacity, poor rate performance and low cyclability, due to the poor electronic and ionic conductivity. Herein, a series of high-performance conjugated-quinones@MXene hybrid cathodes is constructed by an in situ polymerization-assembly strategy based on the hydrogen bond and S-Ti interaction. The PAQS@Ti3C2Tx MXene hybrid, as a typical example, exhibits sandwiched structure with intimate PAQS@MXene contact, resulting in efficient interfacial mass transfer. The assembled MXene is able to build interconnected conductive channels in the hybrid cathodes for continuous and fast electrons/ions transport, which is verified by both the experimental results and density functional theory (DFT) calculations. As a result, the optimal PAQS@MXene hybrid electrode delivers excellent electrochemical performances with high capacity (∼242 mA h g-1 at 100 mA g-1), superior fast-charge/discharge ability (∼148 and 121 mA h g-1 at 5 and 10 A g-1, respectively), and ultralong cycle life (capacity as high as 57 mA h g-1 after 9000 cycles at 5 A g-1), which are more superior to that of the pure PAQS electrodes. Besides, the analogous PPTS@Ti3C2Tx MXene hybrid cathode also shows better performances compared to the pure materials.
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