木筏
化学
试剂
链式转移
点击化学
高分子化学
叠氮化物
氟化物
可逆加成-断裂链转移聚合
聚合物
环加成
聚合
除氧
功能性聚合物
组合化学
作者
Jingrui Liu,Wei Sun,Zhaoqiang Wu,Hong Chen
出处
期刊:Journal of Polymer Science
[Wiley]
日期:2022-03-31
卷期号:60 (13): 1954-1961
被引量:1
摘要
A novel trithiocarbonate reversible addition−fragmentation chain transfer (RAFT) reagent, 3-azidopropyl (4-[fluorosulfonyl]benzyl)trithiocarbonate (Az-FSBCT), which has both clickable azidopropyl and sulfonyl fluoride moieties, was designed and synthesized. Using the RAFT agent Az-FSBCT and triethylboron as an initiator, well-defined poly(N-vinylpyrrolidone) (PVP), in which the azide and sulfonyl fluoride groups are at the α and ω positions of the polymer chains, were prepared without prior deoxygenation at room temperature. Moreover, the possibilities for the construction of new functionalized polymers were also demonstrated by a “click” copper(I)-catalyzed alkyne-azide cycloaddition (CuAAC) and sulfur(VI)-fluoride exchange (SuFEx) postreaction using these terminal functional PVPs.
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