超级电容器
化学
熔盐
木屑
碳纤维
化学工程
多孔性
电化学
盐(化学)
电容
功率密度
微观结构
无机化学
电极
有机化学
复合材料
材料科学
结晶学
功率(物理)
物理化学
工程类
物理
复合数
量子力学
作者
Lvye Yang,Jianhao Qiu,Yaquan Wang,Shihang Guo,Yi Feng,Dehua Dong,Jianfeng Yao
标识
DOI:10.1016/j.jelechem.2019.113673
摘要
Molten salt synthesis is applied in the preparation of porous carbon under air atmosphere. Wood sawdust is used as the carbon source, and the molten salt containing KCl and KOH acts as structure-directing agent to tailor microstructure of porous carbon, making the resulting carbon have improved electrochemical performance. The function of molten salt is controlled by the cooperation of KCl and KOH in different compounding ratios. Benefiting from the open pore structure, the optimized carbon (CS-H3) shows the highest specific capacitance of 286 F g−1 in 1 A g−1, and the energy density reaches 5.63 W h kg−1 at a power density of 9213 W kg−1 in 6 M KOH. Furthermore, CS-H3 also displays an excellent cycle life of high capacitance retention of 99.8% after 10,000 cycles. This work provides a high-efficiency route to prepare hierarchical porous carbon from biomass, showing a promise in the industrial production.
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