This paper reports the piezoelectric properties of ScAlN thin films. We evaluated the piezoelectric coefficients d 33 and d 31 of Sc x Al 1-x N thin films directly deposited onto silicon wafers, as well the radio frequency (RF) electrical characteristics of Sc 0.35 Al 0.65 N bulk acoustic wave (BAW) resonators at around 2 GHz, and found a maximum value for d 33 of 28 pC/N and a maximum -d 31 of 13 pm/V at 40% scandium concentration. In BAW resonators that use Sc 0.35 Al 0.65 N as a piezoelectric film, the electromechanical coupling coefficient k 2 (=15.5%) was found to be 2.6 times that of resonators with AlN films. These experimental results are in very close agreement with first-principles calculations. The large electromechanical coupling coefficient and high sound velocity of these films should make them suitable for high frequency applications.