化学
卟啉
茴香醚
氯乙酸
钴
锌
催化作用
铜
镍
产量(工程)
溶剂
水溶液中的金属离子
金属
无机化学
配位复合体
高分子化学
有机化学
核化学
材料科学
冶金
出处
期刊:Chemical Reagents
日期:2014-01-01
被引量:1
摘要
The reaction conditions were explored for the synthesis of meso-5,10,15,20-tetrakis(4-isopropylphenyl) porphyrin in organic solvents catalyzed by organic acid,and optimized the reaction conditions between porphyrin and metal ions,then cobalt(Ⅱ),nickel(Ⅱ),copper(Ⅱ),zinc(Ⅱ),lead(Ⅱ) and vanadyl(Ⅱ) metal porphyrins have been synthesized.The results showed that the yield of porphyrin up to 25.28% by using anisole as the solvent and catalyzed by chloroacetic acid.The structure was confirmed by elemental analysis,UV-Vis and1HNMR.
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