胶粘剂
材料科学
乙二醛
差示扫描量热法
木质素
苯酚
热稳定性
抗弯强度
合成树脂
固化(化学)
酚醛树脂
复合材料
热重分析
化学工程
有机化学
化学
工程类
物理
热力学
图层(电子)
作者
Hamed Younesi-Kordkheili,A. Pizzi
出处
期刊:Futures for small speculators
[Taylor & Francis]
日期:2019-04-03
卷期号:96 (16): 1385-1395
被引量:21
标识
DOI:10.1080/00218464.2019.1600405
摘要
Investigation of the properties of particleboard panels bonded with a phenol-lignin-glyoxal (PLG) resin as a new type of wood adhesive was the aim of this research work. Thus, various contents of soda bagasse lignin (20, 30 and 40 wt%) as a substitute of part of the phenol were used to synthesize PLG resins, coupled with glyoxal as a nontoxic aldehyde. The resins prepared were then used to bond particleboard panels. The physicochemical properties of the synthesized resins and physical and mechanical properties of the particleboard panels bonded with the PLG resins were measured. The thermal properties of the resins were also analyzed by Differential Scanning Calorimetry (DSC). Finally, the properties of the resins and of the panels bonded with them were compared with those of a control PF resin and the relevant EN standards. The results showed that PLG resins, especially at the higher percentages of lignin, had slower gel time and lower viscosity compared to the control PF resin. DSC analysis also indicated that curing of a PLG resin with 30 wt% lignin substitution needs a higher temperature than for a PF resin. Although the panels bonded with PLG resins presented weaker mechanical properties and lower dimensional stability compared to those bonded with PF resins their properties still satisfy the requirements of the relevant standards specifications. The results of this work indicated that panels bending and internal bond strengths, as well as their dimensional stability, decrease with an increasing percentage of the lignin content from 20% to 40% by weight, while the flexural modulus increases.
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