FeAlPO-5 catalysts have been synthesized by hydrothermal method and investigated in the catalytic reduction of N2O with CH4. The catalysts exhibit good low temperature activity. The XRD and SEM characterization indicate there are Fe(II) species over high iron content FeAlPO-5 catalyst, which play important role in the reaction. The catalytic conversion of N2O over FeAlPO-5 was effectively promoted by the addition of CH4.