镧系元素
化学
路易斯酸
羧酸盐
组合化学
金属有机骨架
催化作用
选择性
无机化学
竞争性约束
作者
Jun Yan,Xinhui Dong,Yishan Hou,S.M Liu,Yue Yan,Xinyuan Mao,Yongxin Li,Yunyi Cui,Jian Lin
摘要
A fluorochromic Eu-based MOF is developed for highly selective Zr(IV) detection. Leveraging the strong Lewis acidity of Zr(IV), competitive coordination to carboxylate sites induces framework dissociation, disrupts ligand-to-metal energy transfer,...
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