Investigation on the catalytic behavior of a novel thulium-organic framework with a planar tetranuclear {Tm4} cluster as the active center for chemical CO2 fixation

The exquisite combination of coplanar {Tm 4 } clusters and structure-oriented functional BDCP 5− leads to a highly robust nanoporous Tm-MOF (NUC-37) with high catalytic performance on the chemical fixation of CO 2 .