Stimuli‐Responsive Supramolecular Polymers from Amphiphilic Phosphodiester‐Linked Azobenzene Trimers

Abstract An amphiphilic phosphodiester‐linked azobenzene trimer has been exploited in the development of stimuli‐responsive, water‐soluble supramolecular polymers. The trimer can reversibly undergo thermal and photoisomerization between Z‐ and E‐isomers. Its self‐assembly properties in aqueous medium have been investigated by spectroscopic and microscopic techniques, demonstrating that E‐ and Z‐azobenzene trimers form supramolecular nanosheets and toroidal nanostructures, respectively. By virtue of the E/Z photoisomerization of the azobenzene units, the two different supramolecular morphologies can be switched by photoirradiation. The findings pave a way towards stimuli‐responsive, water‐soluble supramolecular polymers which hold great promise in the development of smart functional materials.