立体光刻
复合数
材料科学
复合材料
填料(材料)
散射
粒子(生态学)
聚甲基丙烯酸甲酯
光散射
折射率
光致聚合物
粒径
聚合物
光学
化学工程
光电子学
物理
地质学
工程类
海洋学
聚合
作者
Guanghai Fei,Cesar Parra‐Cabrera,Kuo Zhong,Max L. Tietze,Koen Clays,Rob Ameloot
出处
期刊:ACS applied polymer materials
[American Chemical Society]
日期:2021-11-24
卷期号:3 (12): 6705-6712
被引量:16
标识
DOI:10.1021/acsapm.1c01519
摘要
Fillers are used to modify the properties of the photoresins used in stereolithography (SLA). The resulting composite formulations tend to have a decreasing cure depth for increasing particle loadings due to light scattering. However, some composites, such as those loaded with silica or polymethyl methacrylate particles, show the opposite effect: the cure depth increases with the particle loading. To unify these seemingly contradictory observations, we propose a modified Lambert–Beer equation. Depending on the filler properties, we differentiate between three scenarios: (i) scattering-dominated, (ii) weakly scattering, and (iii) nonscattering (refractive index-matched). In the first case, the cure depth of the resin decreased with an increasing solid loading, whereas in the other cases, the opposite trend was observed. These findings have significant implications for the formulation of composite SLA resins in terms of materials selection and printing parameter optimization.
科研通智能强力驱动
Strongly Powered by AbleSci AI