沥青质
堆积
插层(化学)
化学
共轭体系
拉曼光谱
芳香性
透射电子显微镜
化学工程
粘度
有机化学
结晶学
材料科学
分子
聚合物
物理
光学
复合材料
工程类
作者
Jie Yu,Hongping Quan,Jia Xiao,Jingran Wang,Lilong Zhang,Xuefei Chang,Shuaibin Peng,Jinyu Wang,Zhiyu Huang
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2024-08-23
卷期号:38 (17): 16056-16065
被引量:1
标识
DOI:10.1021/acs.energyfuels.4c02332
摘要
Based on dispersing the stacking structure of asphaltenes and inhibiting the reaggregation of asphaltenes, functional chitosan oligosaccharide (COS) derivatives were prepared using COS in this study. Driven by the conjugated intercalation of aromatic rings, COS derivatives could move among the lamellae of asphaltene stacked structures. The effect of COS derivatives on asphaltene aggregates for face-to-face stacking and the inner diameter of the aromatic sheet was characterized by X-ray diffraction and Raman. The microstructure of asphaltene in this mode of interaction could be observed by field emission scanning electron microscopy and high-resolution transmission electron microscopy. The effect of COS derivatives on the stacking structure and aggregation behavior of asphaltenes could enhance the fluidity of heavy oil, resulting in a change in the viscosity-temperature curve of heavy oil. This demonstrates the enormous research value of COS derivatives in the extraction and transportation of heavy oil.
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