Flexible hydrogen-bonded organic frameworks (HOFs): opportunities and challenges

While some other flexible porous materials have been extensively studied, the dynamic behavior of HOFs remains relatively less explored. This perspective highlights the inherent flexible properties of HOFs, discusses their different flexible behaviors, including pore size/shape changes, interpenetration/stacking manner, H-bond breaking/reconstruction, and local dynamic behavior, and highlights their potential applications. We believe that this perspective will not only contribute to HOF chemistry and materials science, but will also facilitate the ongoing extensive research on dynamic porous materials.