化学
缺氧水域
氧化还原
过氧化氢
氧气
产量(工程)
羟基自由基
光化学
生物地球化学循环
激进的
过氧化氢酶
无机化学
过氧化物
腐植酸
环境化学
有机化学
抗氧化剂
材料科学
冶金
肥料
作者
Sarah E. Page,Michael Sander,William A. Arnold,Kristopher McNeill
摘要
Humic acids (HAs) accept and donate electrons in many biogeochemical redox reactions at oxic/anoxic interfaces. The products of oxidation of reduced HAs by O2 are unknown but are expected to yield reactive oxygen species, potentially including hydroxyl radical (·OH). To quantify the formation of ·OH upon oxidation of reduced HAs by O2, three HAs were reduced electrochemically to well-defined redox states and were subsequently oxidized by O2 in the presence of the ·OH probe terephthalate. The formation of ·OH upon oxidation increased with increasing extent of HA reduction. The yield of ·OH ranged from 42 to 160 mmol per mole of electrons donated by the reduced HA. The intermediacy of hydrogen peroxide (H2O2) in the formation of ·OH was supported by enhancement of ·OH formation upon addition of exogenous H2O2 sources and by the suppression of ·OH formation upon addition of catalase as a quencher of endogenous H2O2. The formation of ·OH in the dark during oxidation of reduced HA represents a previously unknown source of ·OH formation at oxic/anoxic interfaces and may affect the biogeochemical and pollutant redox dynamics at these interfaces.
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