Decarboxylative C(sp3)–S Coupling via Cu–Photoredox Catalysis

In this issue of Chem, Liu, Li, and co-workers report the synergistic use of copper and photoredox catalysis to reveal a general platform to form C(sp3)–S bonds via redox-active esters of abundantly available aliphatic carboxylic acids with organosulfinates under mild conditions.