共价键
多孔性
化学
金属有机骨架
金属
材料科学
化学工程
纳米技术
有机化学
工程类
吸附
作者
Shuyin Peng,Yuqian Sun,Qingqing Li,Zhuo Jiang,Yin Rao,Yanxin Wu,Qiaowei Li
摘要
A cyclic trinuclear complex is synthesized from AgI and 1H-pyrazole-4-carbaldehyde. Reticulation of the complex with 1,3,5-tris(4-aminophenyl)benzene through Schiff-base reaction affords a porous FDM-72 framework. Amine choice is systematically investigated as it may initiate metal reduction. This study proposes a new route and its amine selection criterion to synthesize Ag-based frameworks.
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