荧光粉
能量转移
锂(药物)
铝酸盐
没食子酸
材料科学
矿物学
工程物理
光电子学
化学
冶金
物理
核化学
医学
水泥
内分泌学
作者
Yi-Ting Tsai,Pei-Xuan Chen,Mikołaj Kamiński,Natalia Majewska,Sebastian Mahlik,Mu‐Huai Fang
标识
DOI:10.1021/acsaom.3c00464
摘要
Short-wave infrared (SWIR) phosphor-converted light-emitting diode (LED) technology holds promise for advancing broadband light sources. Despite the potential, limited research has delved into the energy transfer mechanism from sharp-line to broadband emission in SWIR phosphors, which remains underexplored. Herein, we demonstrate bright SWIR phosphors achieved through Cr3+/Ni2+ energy transfer in LiGa5(1–x)Al5xO8. High-resolution X-ray diffraction revealed the typical solid solution and distortion occurring in Al3+ octahedral sites. In addition, the X-ray absorption spectrum illustrates that Cr3+ and Ni2+ have different coordination environments, showing the possibility that they occupy different positions or that the coordinated environment of Ni2+ is distorted due to charge imbalance. Temperature-dependent studies provide insights into the energy transfer dynamics between Cr3+/Ni2+, from the 2E level of Cr3+ (sharp band) to the 3T1 level of Ni2+ (broadband). The increased emission intensity at lower temperatures in the x = 0.6 and x = 1.0 samples can be explained by the positioning of the 3T1 level above the 2E level of Cr3+ ions. Finally, we established a mechanism involving a sharp line to broadband energy transfer showcasing a high-power SWIR LED with a radiant power of 21.45 mW.
科研通智能强力驱动
Strongly Powered by AbleSci AI