化学
普鲁士蓝
过氧化氢
过硫酸盐
催化作用
环境修复
金属有机骨架
纳米技术
环境化学
化学工程
无机化学
有机化学
污染
吸附
电化学
电极
物理化学
工程类
生态学
生物
材料科学
作者
Xiaqing Dong,Xuanming Liu,Min Cheng,Danlian Huang,Gaoxia Zhang,Wenjun Wang,Lei Du,Guangfu Wang,Hongda Liu
标识
DOI:10.1016/j.ccr.2023.215067
摘要
Prussian blue (PB) and its analogues (PBAs) are among the oldest Metal-organic frameworks (MOFs) and have been widely studied for their larger surface area, ultra-high porosity, and plentiful active sites. More importantly, its ease of preparation makes it more suitable for practical application than other types of MOFs. The aim of this article is to provide an in-depth overview of the environmental remediation of PB/PBAs in Fenton-like advanced oxidation process (AOPs) (activation of hydrogen peroxide (H2O2) and persulfate (PS, e.g., S2O82−/HSO5−)). First, common synthetic strategies for PB/PBAs-based materials are summarized. Then, the applications of PB/PBAs-based materials in the removal of organic matter and purification of wastewater by Fenton-like oxidation are discussed, with particular attention to their catalytic mechanisms and the identification of reactive oxygen species (ROS). Finally, unresolved challenges and perspectives of the future are proposed. This review provides guidance for the future application and development of PB/PBA in advanced oxidation.
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