酯交换
大豆油
过氧化物
植物油
催化作用
有机化学
产量(工程)
材料科学
化学
制浆造纸工业
化学工程
食品科学
冶金
工程类
作者
Hamdy S. Abdel-Hameed,Shimaa M. Elsaeed,Nehal S. Ahmed,Amal M. Nassar,Ahmed F. El-Kafrawy,Ahmed I. Hashem
标识
DOI:10.1016/j.indcrop.2022.115256
摘要
Bio-based lubricants have traditionally piqued interest as a supplement to mineral oil-based lubricants in response to rising environmental pollution concerns and declining petroleum assets. This paper discussed the synthesis of bio-lubricants from vegetable oils such as soybean (SOY), and jojoba (JOJ) oil using chemical transformation methods such as epoxidation of the carbon-carbon double bonds in the structure of their already high resistance to air oxidation using a combined catalyst of Amberlite IR 120 and peroxide catalyst with high yield (80 %), followed by transesterification, ring-opening of vegetable oils, and finally acetylation of the hydroxylated obtained products. The rheological and tribological characteristics of the compounds produced were examined to validate their suitability as bio-lubricants using FT-IR, 1H NMR, and TGA techniques. These results demonstrate the possibility of an environmentally sustainable method for producing bio-lubricants.
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