Site-engineered Zr-based metal–organic frameworks for ultrahigh-performance one-step separation of methanol-to-olefins products

Oxygen-tailored cage in MOF-808-For enables one-step C 3 H 6 /C 2 H 4 separation: site engineering creates optimal cage size and O-sites for selective C 3 H 6 trapping via multiple C–H⋯O bonds, achieving high selectivity (11.1) and C 2 H 4 productivity (99.1 L kg −1 ).