聚醚酰亚胺
材料科学
膜
甲醇
吸附
化学工程
质子交换膜燃料电池
高分子化学
Nafion公司
聚合物混合物
肿胀 的
聚合物
核化学
复合材料
化学
共聚物
有机化学
物理化学
电极
吸附
工程类
生物化学
电化学
作者
N. Harsha,Swayampakula Kalyani,V. V. Basava Rao,S. Sridhar
出处
期刊:Journal of Fuel Cell Science and Technology
[ASME International]
日期:2015-12-01
卷期号:12 (6)
被引量:12
摘要
Acid–base blends of sulfonated polyethersulfone (SPES) with pristine and aminated polyetherimide (APEI) are synthesized. Three blends polyethersulfone (PES)/polyetherimide (PEI), SPES/PEI, and SPES/APEI are prepared and characterized to evaluate their structural, morphological, mechanical, and other properties. Ion exchange capacity (IEC) of SPES/APEI and SPES/PEI blend membranes was determined to be 3.0 and 2.7 meq g−1, which is a substantial improvement over the 1.0 meq g−1 exhibited by unmodified PES/PEI blend. The proton conductivity of 0.093 S cm−1 displayed by SPES/APEI blend is found to be comparable to that of commercial Nafion membrane (0.056 S cm−1) and far superior to conductivities of 0.091 and 0.082 S cm−1 shown by SPES/PEI and PES/PEI blends, respectively. Further, water sorption observed in case of SPES/APEI and SPES/PEI blends was in the range 17–18% over a soaking time period of 12 hrs, which is ideal for proton conduction accompanied by low-membrane swelling. The methanol permeabilities of SPES/APEI and SPES/PEI blends are found to be 2.5 × 10−7 and 3.47 × 10−7 cm2 s−1, respectively. Compared to unmodified PES/PEI blend which revealed a methanol sorption of 12.3%, the modified blends SPES/PEI (9.6%) and SPES/APEI (7.5%) exhibited much lower methanol uptake over a sorption time of 12 hrs, indicating their capacity for low fuel bypass. The results demonstrate the promising potential of polymer blends made by combining a sulfonated polymer with an aminated polymer, such as SPES/APEI for fuel cell (FC) applications.
科研通智能强力驱动
Strongly Powered by AbleSci AI