What is the coordination number of copper(ii) in metallosupramolecular chemistry?
作者
Val rie Chaurin,Edwin C. Constable,Catherine E. Housecroft
出处
期刊:New Journal of Chemistry [Royal Society of Chemistry] 日期:2006-01-01卷期号:30 (12): 1740-1740被引量:53
标识
DOI:10.1039/b610306e
摘要
Analysis of structural and solution data shows a specific stabilisation of copper(II) in ternary complexes containing one 2,2′:6′,2″-terpyridine and one 2,2′-bipyridine ligand. This is not a general phenomenon relating to five-coordinate copper(II), but rather a specific consequence of the two ligand donor sets. The consequences of this observation for metallosupramolecular chemistry are discussed.