生物炭
热解
芳香性
傅里叶变换红外光谱
产量(工程)
材料科学
微波食品加热
燃烧热
化学
碳纤维
化学工程
核化学
有机化学
复合材料
分子
燃烧
工程类
物理
复合数
量子力学
作者
Tom Haeldermans,Jürgen Claesen,Jens Maggen,Robert Carleer,Jan Yperman,Peter Adriaensens,Pieter Samyn,Dries Vandamme,Ann Cuypers,Kenny Vanreppelen,Sonja Schreurs
标识
DOI:10.1016/j.jaap.2018.12.027
摘要
Two different heat treatments for MDF, microwave assisted pyrolysis (MWP) and conventional pyrolysis (CPS), are investigated. The influence of different microwave absorbers (activated carbon (AC) and K2CO3) and different microwave powers in MWP and different temperatures in CPS on the characteristics of biochar is reviewed. Morphology and chemical properties of the obtained biochars are evaluated comparing biochar yield, ultimate analysis, proximate analysis, biochar stability test, FTIR spectroscopy and solid-state 13C CP/MAS NMR spectroscopy. The resulting biochars of both processes are compared to find the best production method. An increasing microwave power without the use of MWA, leads to a higher degree of aromaticity. The addition of increasing amounts of AC at low microwave power (300 W) leads to higher pyrolysis temperatures and more aromatic biochars. At 400 W a more aromatic biochar with a more open surface is achieved compared to 300 W. However, the addition of an increasing amount of AC as a MWA at 400 W induces a lower pyrolysis temperature with increasing biochar yields and decreasing aromaticity. K2CO3 is more effective as a MWA and produces more aromatic biochar at lower microwave power than when using AC. In general MWP yields a biochar with a higher degree of aromaticity at lower temperatures than CPS. Both CPS and MWP are viable options for transforming MDF into a value added biochar.
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