化学
硫黄
芳基
氯化物
碳酸二甲酯
有机化学
溶剂
催化作用
碳酸盐
烷基
作者
Ren-Guan Miao,Xinxin Qi,Xiao‐Feng Wu
标识
DOI:10.1002/ejoc.202101037
摘要
Abstract A new procedure for the synthesis of aryl methyl sulfides from dimethyl carbonate (DMC) and arylsulfonyl chlorides has been achieved. In this strategy, DMC plays a dual role as both, C1 building block and green solvent. Arylsulfonyl chlorides served as the sulfur precursors, and a variety of aryl methyl sulfides were obtained in moderate to excellent yields with good functional group tolerance. Additionally, alkylsulfonyl chloride and dibenzyl carbonate are proven to be suitable substrates as well.
科研通智能强力驱动
Strongly Powered by AbleSci AI