V-shaped bis-coumarin based fluorescent probe for detecting palladium in natural waters

A catalytic fluorescent probe based on V-shaped bis-coumarin has been designed and synthesized for detection of palladium (Pd). The detection mechanism of the probe is based on palladium-catalyzed Tsuji‒Trost reaction process and photoinduced electron transfer (PET), which can distinguish and detect palladium (0, +2/+4) in different valence states under different conditions. The fluorescence intensity of the probe enhances after adding the palladium in about 10 min at room temperature. The limit of detection (LOD) of the probe is as low as 40.0 nM (4.2 ng/g), and it has good selectivity and high sensitivity. Apart from that, it has been successfully applied to detection of palladium in environmental waters.