吸附
化学吸附
硫酸
介电谱
化学
电化学
动力学
无机化学
碳纤维
活化能
核化学
碳钢
材料科学
物理化学
电极
有机化学
腐蚀
复合材料
复合数
物理
量子力学
作者
Ya. G. Avdeev,A. Yu. Luchkin,Yu. I. Kuznetsov
标识
DOI:10.1134/s2070205120070035
摘要
The method of electrochemical impedance spectroscopy was used to study the adsorption of an IFKhAN-92 inhibitor, 3-substituted 1,2,4-triazole, on low-carbon steel from 2.0 M H2SO4 (22°C). It was shown that the Temkin isotherm with a relatively high value of free energy of adsorption (−ΔGads) = 49 kJ/mol described its adsorption. It was suggested that the inhibitor adsorption has a chemisorption nature, which is testified both by the description of the kinetics of adsorption by the Roginsky–Zeldovich equation and a high protective aftereffect of the inhibitor adsorbed on the steel surface.
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