吸附
腐蚀
朗缪尔吸附模型
碳钢
介电谱
三嗪
扫描电子显微镜
电化学
三聚氰胺
化学
无机化学
核化学
材料科学
有机化学
物理化学
复合材料
电极
作者
Cunhua Wei,Ge Xu,Jin Yu
标识
DOI:10.1002/maco.202113020
摘要
Abstract A novel triazine derivative, 2, 4‐diamino‐6‐dodecamido‐1, 3, 5‐triazine (DT), is synthesized by the dehydration condensation of melamine and lauric acid, and its inhibitive performances for the corrosion of Q235 carbon steel in 1 mol/L HCl solution is investigated by electrochemical polarization, electrochemical impedance spectroscopy, scanning electron microscopy, and atomic force microscope. The results reveal that its best inhibition efficiency reaches 96.98% at a concentration of 2.5 g/L. The calculation results of kinetic and thermodynamic parameters indicate that the adsorption of DT on carbon steel surface obeys Langmuir adsorption isotherm with both physical and chemical adsorption. It is demonstrated that long‐chain amide (>8C) substituted 1, 3, 5‐triazine derivative has the synergistic corrosion inhibition effect of the surface fixation on metal iron and the hydrophobic adsorption layer.
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