光催化
产量(工程)
光致发光
兴奋剂
吸附
材料科学
石墨氮化碳
载流子
光化学
傅里叶变换红外光谱
可见光谱
化学工程
化学
催化作用
光电子学
有机化学
复合材料
工程类
作者
Jiyeon Park,Hao Líu,Guangxia Piao,Unseock Kang,Hae Yong Jeong,Csaba Janáky,Hyun Woong Park
标识
DOI:10.1016/j.cej.2022.135388
摘要
Achieving high-efficiency photocatalytic conversion of CO2 into value-added chemicals remains a challenge. This study synthesizes In-doped TiO2 and g-C3N4 composites (In-TiO2/g-C3N4) via a facile and reliable method. The as-synthesized In-TiO2/g-C3N4 produces CO, CH4, and C2H4 under UV, and CO and CH4 under visible light from gaseous CO2 and H2O vapor. A prolonged photocatalysis results in the continuous production of the same set of carbonaceous compounds over 30 h, with a photonic yield of ∼ 40%. The yield of C2H4 with In-TiO2/g-C3N4 is ∼ 11-times greater than the sum of In-TiO2 and g-C3N4. The CO2 adsorption isotherms show that In-TiO2 acts as a CO2 adsorbent and photocatalyst whereas g-C3N4 mainly works as a photocatalyst. In-situ FTIR study reveals the formation of CH4 and C2H4 on In-TiO2/g-C3N4. Time-resolved photoluminescence indicate that In-doping facilitates charge transfer and a strongly coupled g-C3N4 induces cascaded charge transfer. This leads to inhibited charge recombination and long-lived charge carriers.
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