Synergistic effects of oxidation, coagulation and adsorption in the integrated fenton-based process for wastewater treatment: A review

Fenton process is the most popular for wastewater treatment among all available advanced oxidation processes (AOPs). Numerous endeavors have been devoted to improving the oxidation efficiency of Fenton reaction in terms of promoting ·OH generation, accelerating iron redox cycle and extending applicable pH range. However, in addition to oxidation, coagulation and adsorption also simultaneously occur in the Fenton process, which play important role in the removal of pollutants. Rapid progress has revealed the synergistic effects of oxidation, coagulation and adsorption in the Fenton process, providing new ideas for the treatment of complex and refractory wastewater. Based on available studies, this review is the first to systematically summarize the research progress regarding the synergistic effects of oxidation, coagulation and adsorption in the integrated Fenton-based processes for wastewater treatment. The involved mechanism of the synergistic effects in different Fenton processes (homogeneous Fenton, heterogeneous Fenton and physical field-assistant Fenton coupling process) are critically reviewed. Furthermore, special attention has been paid to the representative applications of the synergistic effects in wastewater treatment (such as industrial organic wastewater, landfill leachate and heavy metal-organic complexes, etc.), particularly focusing on the operation parameters and removal performance. Finally, a conclusion of the review and subsequently, perspectives are given for possible research directions. We believe this review can provide useful information for researchers and end-users involved in the development and application of the Fenton process in wastewater treatment.