薄膜
材料科学
电场
反铁电性
电介质
铁电性
四方晶系
储能
电容器
相(物质)
光电子学
电气工程
纳米技术
电压
化学
物理
工程类
功率(物理)
量子力学
有机化学
作者
Duandan Shangguan,Yinuo Duan,Binglei Wang,Chao Wang,Jiaxin Li,Yu Bai,Fan Zhang,Yizhuo Li,Yusheng Wu,Zhan Jie Wang
标识
DOI:10.1016/j.jallcom.2021.159440
摘要
In this work, (1-x)PbZrO3-xPbSnO3 (PZO-PSO) antiferroelectric thin films were prepared on Pt(111)/Ti/SiO2/Si substrates by a sol-gel method in order to improve energy-storage performances under low electric fields, and the effects of PSO content on microstructures, electrical performances and energy storage behaviors of the thin films were studied in-detail. The results showed that doping PSO in PZO thin films can reduce the stability of antiferroelectric phase, thus ferroelectric polarization of the thin films can reach a lager value at low electric fields. Meanwhile, polyphase components including tetragonal and orthorhombic phase were generated in the PZO-PSO thin films, leading to diffusive phase transition from antiferroelectric to ferroelectric phase under the electric field. Hence, the energy storage behaviors of the PZO-PSO thin films under low electric field were improved significantly. When PSO content was x = 0.48, its energy storage density and efficiency reached the maximum values of 6.11 J/cm3 and 72% at 333 kV/cm, which was 68.26% and 10% higher than pure PZO thin films, respectively. Our results will lay a solid foundation for developing energy-storing antiferroelectric thin films for the application of dielectric capacitors at low electric fields.
科研通智能强力驱动
Strongly Powered by AbleSci AI