Main‐Side Chain Hydrogen Bonding‐Based Self‐Healable Polyurethane with Highly Stretchable, Excellent Mechanical Properties for Self‐Healing Acid–Base Resistant Coating

Developing an autonomous self-healing polyurethane (PU) elastomer with excellent mechanical properties and high ductility has attracted increasing attention. Nowadays, the synthesis of elastomers with excellent mechanical properties and rapid self-healing at room temperature faces a huge challenge. Herein, This work reports a new supramolecular PU with excellent mechanical properties and rapid self-healing at room temperature through the introduction of T-type chain extender into the supramolecular polymer chain. The introduction of T-chain extender can be used to enhance the mechanical strength of PU, and the multiple hydrogen bonds on the side-chain provide theoretical support for the rapid self-healing ability of PU. Maximum stress of the synthesized PU can reach 3.4 ± 0.15 Mpa, and maximum elongation at break can reach 3200% ± 160%. Due to flexibility and re-constructability of side-chain hydrogen bonds, PU stress repair efficiency can reach 96.7%, and can be self-healing scratches rapidly and effectively at room temperature. The mechanical properties and self-healing properties of PU can be adjusted by the content of T-type chain extender. The PU is applied to the metal surface coating, which has excellent acid-base resistance, bond strength up to 2.9 ± 0.1 Mpa, and the ability to eliminate local damage on the coating surface quickly at room temperature.