化学发光
光化学
猝灭(荧光)
化学
电解
碳氢化合物
单线态氧
氧气
激发态
阴极
单重态
无机化学
荧光
电极
有机化学
物理化学
物理
核物理学
电解质
量子力学
出处
期刊:Science
[American Association for the Advancement of Science (AAAS)]
日期:1964-08-21
卷期号:145 (3634): 808-809
被引量:272
标识
DOI:10.1126/science.145.3634.808
摘要
Chemiluminescence is reported from chemical species produced during electrolysis of aromatic hydrocarbons in deoxygenated nonaqueous solvents. Emission occurs in the solution near the cathode, and the emitting species is the excited singlet state of the hydrocarbon. Oxygen exerts a severe quenching effect on the chemiluminescence. Possible mechanisms are discussed.
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