Oxidizing Morita–Baylis–Hillman adducts towards vicinal tricarbonyl compounds
邻接
氧化剂
加合物
化学
立体化学
有机化学
作者
Marília S. Santos,Fernando Coelho
出处
期刊:RSC Advances [The Royal Society of Chemistry] 日期:2012-01-01卷期号:2 (8): 3237-3237被引量:37
标识
DOI:10.1039/c2ra01267g
摘要
We disclose herein a simple and direct method to synthesize vicinal tricarbonyl compounds (VTC) from Morita–Baylis–Hillman (MBH) adducts. The method is based on two sequential oxidation steps which provide VTC in moderate to good yields. This is the first report of the synthesis of vicinal tricarbonyl compounds from MBH adducts.