碱金属
锆
离域电子
钛
结晶学
插层(化学)
材料科学
金属
电子离域
离子
化学
无机化学
物理化学
冶金
有机化学
作者
A. Leblanc‐Soreau,M. Danot,Léa Trichet,J. Rouxel
标识
DOI:10.1016/0025-5408(74)90198-6
摘要
A general survey of alkali metals intercalation compounds with titanium and zirconium disulfides is given. A model A+x (Ti S2x− or A+ (Zr S2)x− with an electronic delocalization in the (Ti2S2) or (Zr S2) slabs, is suggested according to crystallographic and magnetic studies, N.M.R. measurements, and chemical behaviour. The alkali metal coordination is related to several factors: size of the A+ ion, value of the x parameter, strength of the T.S. bonds.
科研通智能强力驱动
Strongly Powered by AbleSci AI