化学
抗坏血酸
芳基
亚硝酸盐
苯胺
亚硝化
硫化物
金属
产量(工程)
有机化学
维生素C
药物化学
组合化学
烷基
材料科学
冶金
硝酸盐
食品科学
作者
Mei‐jie Bu,Guo‐ping Lu,Chun Cai
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2015-07-16
卷期号:26 (13): 1841-1846
被引量:22
标识
DOI:10.1055/s-0034-1378738
摘要
A mild, metal-free synthesis of aryl sulfides has been disclosed. Aryl diazonium ion was generated by the in situ nitrosation of aniline, and it was reduced by ascorbic acid (vitamin C) to form aryl radical, which underwent a thiolation with disulfide to yield aryl sulfide. The reaction proceeded smoothly without heating or irradiation. This strategy was also expanded to the synthesis of aryl selenides.
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