Molecular Design of Active Layer for High‐Performance Stretchable Organic Solar Cells

Stretchable organic solar cells (SOSCs) have advanced rapidly in the last few years as power sources required to realize portable and wearable electronics become available. Through rational material and device engineering, SOSCs are now able to retain their photovoltaic performance even when subjected to repeated mechanical deformations. However, reconciling a high efficiency and an excellent stretchability is still a huge challenge, and the development of SOSCs has lagged far behind that of flexible OSCs. In this perspective article, recent strategies for imparting mechanical robustness to SOSCs while maintaining high power conversion efficiency are reviewed, with emphasis on the molecular design of active layers. Initially, an overview of molecular design approaches and recent research advances is provided in improving the stretchability of active layers, including donors, acceptors, and single-component materials. Subsequently, another common strategy for regulating photovoltaic and mechanical properties of SOSCs, namely multi-component system, is summarized and analyzed. Lastly, considering that SOSCs research is in its infancy, the current challenges and future directions are pointed out.