推进剂
高氯酸铵
材料科学
氢键
聚丁二烯
复合数
高能材料
极限抗拉强度
化学工程
高分子化学
复合材料
化学
分子
有机化学
爆炸物
聚合物
共聚物
工程类
作者
Pingan Zhang,Lei Sun,Jianmin Yuan,Jiyong Deng
标识
DOI:10.1016/j.dt.2023.06.009
摘要
To simplify the composite propellant formulation and address the current issue of the single-functionality present in existing additives, the multi-cyano, amine-based polybutadiene (AEHTPB-CN) was prepared based on AEHTPB by adopting appropriate synthesis strategies. By replacing 10% of HTPB binder in the propellant formulation, it can effectively enhance the interfacial bond strength between the propellant binder matrix and solid fillers (AP (ammonium perchlorate) and RDX (cyclotrimethylene-trinitramine)), the mechanical properties of the HTPB/AP/RDX/Al propellant were superior to blank control propellant with an improvement of 35.4% in tensile strength, 62.0% enhancement in elongation at break, and reduce the propellant burn rate by 10.7% with any energy loss. The function mechanism of AEHTPB-CN was systematically elucidated through experiments and computer simulation techniques. The results show that the tertiary amine group in AEHTPB-CN can react with AP to form ammonium ionic bonds, and the hydroxyl and cyano groups can form hydrogen bonding interactions with AP, which enables AEHTPB-CN to be firmly adsorbed on the AP surface through chemical and physical interactions. For RDX, the interfacial bonding effect of AEHTPB-CN is attributed to their ability to form C–H⋅⋅⋅NC weak hydrogen bonding interaction between the cyano group and RDX methylene group.
科研通智能强力驱动
Strongly Powered by AbleSci AI