发光
材料科学
晶体结构
纳米技术
离子
光致发光
兴奋剂
光电子学
Crystal(编程语言)
红外线的
化学
结晶学
计算机科学
光学
物理
有机化学
程序设计语言
作者
Yi Wei,Peipei Dang,Zhenhong Dai,Guogang Li,Jun Lin
标识
DOI:10.1021/acs.chemmater.1c01325
摘要
Near-infrared (NIR) luminescent materials are attracting much attention as the promising applications in food composition analysis, night vision, biosensors, and so on. Besides Cr3+ ions, other ions such as Eu2+, Ce3+, and Bi3+, etc. recently also exhibit remarkable broadband NIR light emission in inorganic hosts. The key issues are to optimize their photoluminescence quantum yield and reveal an unclear “structure-luminescence” relationship. Herein, photoluminescence properties of NIR luminescent materials without Cr3+ are systematically summarized. Importantly, we propose a significant influence of local crystal structure on NIR luminescence properties. These strategies contain (i) ligand covalency, (ii) strong crystal field and distorted lattice, (iii) selective sites occupation, and (iv) mixed valences and doping level control. The proposed “structure-luminescence” relationship can provide a new insight into exploit NIR luminescent materials and optimize current luminescent materials. Furthermore, the concept of “high-throughput DFT prediction-crystal structure design-photoluminescence performances optimization” is summarized to swiftly develop targeted NIR luminescent materials. Subsequently, energy transfer strategies and application prospects are summarized in detail. This review discusses the relationship between crystal structure and NIR light emission based on a high-throughput method. The proposed concept can offer a guidance to exploit a series of novel NIR luminescent materials and clarify underlying luminescence mechanisms.
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