异质结
材料科学
光降解
降级(电信)
光催化
化学工程
制作
光电子学
四环素
纳米技术
化学
计算机科学
催化作用
有机化学
工程类
病理
电信
医学
替代医学
抗生素
生物化学
作者
Rui Peng,Youxin Kang,Xiaohao Deng,Xiaoming Zhang,Fang Xie,Haiyan Wang,Wenwen Liu
标识
DOI:10.1016/j.jece.2021.106750
摘要
Heterojunction engineering, especially face-to-face heterojunction, is considered as a serviceable approach to manipulate the activity of photocatalysts. Herein, a face-to-face heterojunction of BiOCl/Bi2WO6 was fabricated by a simple in situ topotactic transformation process. By using BiOCl sheets as building block, a close and face-contact BiOCl/Bi2WO6 heterointerface was obtained because Bi2WO6 sheets were generated on the surface of BiOCl sheets through metathesis Cl- with WO42-. The obtained heterojunctions were characterized by various methods to identify the successful preparation and characteristics. The photocatalytic activities of BiOCl/Bi2WO6 heterojunctions were investigated under visible light irradiation by degradation of tetracycline hydrochloride aqueous solution. The experimental results suggested that BiOCl/Bi2WO6 heterojunctions exhibit significant enhanced efficiency for tetracycline hydrochloride degradation compared with pure BiOCl. The enhanced activity can be attributed to the efficient carrier separation and transfer benefiting from lots of carrier transfer channels in heterointerface and extended visible light harvesting ability of Bi2WO6. The work highlights that the fabrication of heterojunctions by constructing close and large-area contact heterointerface is beneficial to enhance the pollutant degradation activity.
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