Electrolysis Synthesis of Carbides and Carbon Dioxide Capture in Molten Salts

Abstract The application of carbides in catalysis, batteries, aerospace fields, etc. has been continuously expanded and deepened, which is attributed to the diversified physicochemical properties of carbides via a tune‐up of their morphology, composition, and microstructure. The emergence of MAX phases and high entropy carbides with unparalleled application potential undoubtedly further stimulates the research upsurge of carbides. The traditional pyrometallurgical or hydrometallurgical synthesis of carbides inevitably faces the shortcomings of complex process, unacceptable energy consumption, extreme environmental pollution, and beyond. The molten salt electrolysis synthesis method with the superiorities of straightforward route, high efficiency, and environmental friendliness has demonstrated its validity in the synthesis of various carbides, which naturally initiates more research. In particular, the process can achieve CO 2 capture while synthesizing carbides based on the excellent CO 2 capture capability of some molten salts, which is of great significance for carbon neutralization. In this paper, the synthesis mechanism of carbide by molten salt electrolysis, the process of CO 2 capture and carbides conversion, the latest research progress in the synthesis of binary, ternary, multi‐component, and composite carbides are reviewed. Finally, the challenges, development perspectives, and research directions of electrolysis synthesis of carbides in molten salts are featured.