化学需氧量
造粒
生物炭
废水
化学
缺氧水域
制浆造纸工业
污水处理
环境化学
核化学
化学工程
材料科学
环境工程
热解
环境科学
有机化学
工程类
复合材料
作者
Dan Li,Shuicheng Yan,Xiaoyu Yong,Xueying Zhang,Jun Zhou
标识
DOI:10.1016/j.scitotenv.2023.163241
摘要
Coal chemical wastewater (CCW) containing toxic and hazardous matters requires to be treated prior to discharge. Promoting the in-situ formation of magnetic aerobic granular sludge (mAGS) in continuous flow reactor process has a great potential for CCW remediation. However, long granulation time and low stability limit the application of AGS technology. In this study, Fe3O4/sludge biochar (Fe3O4/SC) with biochar matrix derived from coal chemical sludge were applied to facilitate the aerobic granulation in two-stage continuous flow reactors, containing separated anoxic and oxic reaction units (abbreviated as A/O process). The performance of A/O process was evaluated at various hydraulic retention times (HRTs) (42 h, 27 h, and 15 h). Magnetic Fe3O4/SC with porous structures, high specific surface area (BET = 96.69 m2/g), and abundant functional groups was successfully prepared by ball-milled method. Adding magnetic Fe3O4/SC to A/O process could promote aerobic granulation (85 days) and the removal of chemical oxygen demand (COD), ammonia nitrogen (NH4+-N), and total nitrogen (TN) from CCW at all tested HRTs. Since the formed mAGS had high biomass, good settling ability, and high electrochemical activities, mAGS-based A/O process had high tolerance to the decrease of HRT from 42 h to 15 h for CCW treatment. The optimized HRT for A/O process was 27 h, at which Fe3O4/SC addition can result in the increase of COD, NH4+-N and TN removal efficiencies by 2.5 %, 4.7 % and 10.5 %, respectively. Based on 16S rRNA genes sequencing, the relative abundances of genus Nitrosomonas, Hyphomicrobium/Hydrogenophaga and Gaiella in mAGS accounting for nitrification, denitrification as well as COD removal were increased during aerobic granulation. Overall, this study proved that adding Fe3O4/SC to A/O process was effective for facilitating aerobic granulation and CCW treatment.
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