多孔性
吸附
形态学(生物学)
化学工程
分散性
聚吡咯
化学
材料科学
核化学
高分子化学
有机化学
聚合物
吸附
聚合
地质学
工程类
古生物学
作者
Hao Yu,Peng Zhang,Hao Chen,Yiming Yao,Leicheng Zhao,Ming‐Hui Zhao,Lingyan Zhu,Hongwen Sun
标识
DOI:10.1016/j.jhazmat.2023.132748
摘要
Herein, a vesicle-like and porous polypyrrole (pPPy) was fabricated by in suit self-template method to efficiently capture per- and polyfluoroalkyl substances (PFASs) and the important role of porosity and morphology in PFAS removal was explored. Compared to solid PPy (sPPy), the porosity and vesicle-like morphology of pPPy endowed it with excellent properties such as large specific surface area (108.9 m2/g vs. 22.3 m2/g), suitable pore sizes (17.4 nm), dispersity, and high hydrophilicity, which facilitated mass transfer and enhanced PFAS sorption performance. The estimated sorption capacities of pPPy for perfluorooctanoic acid (PFOA) and perfluorooctanesulfonate (PFOS) were 509 mg/g and 532 mg/g, respectively, which were ∼2 times higher than sPPy. Furthermore, pPPy demonstrated PFAS removal of ≥ 90% across a wide pH range (3-9) and varying humic acid concentrations (0-50 mg/L). In actual water matrices, pPPy efficiently removed 12 short-chain (C-F number: 3-6) and long-chain PFASs (>90% removal for major PFASs), outperforming sPPy by ∼1.2-2.5 times. Notably, the enlarged porosity and regular morphology of pPPy significantly enhanced the removal of short-chain PFASs by ∼2 times. The spent pPPy could be regenerated and reused over 5 times. This research provides valuable insights for designing efficient PFAS sorbents by emphasizing control over porosity and morphology.
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