Topological Insulator Heterojunction with Electric Dipole Domain to Boost Polysulfide Conversion in Lithium‐Sulfur Batteries

Abstract The heterojunction materials are considered as promising electrocatalyst candidates that empower advanced lithium‐sulfur (Li−S) batteries. However, the detailed functional mechanism of heterojunction materials to boost the sulfur redox reaction kinetics remains unclear. Herein, we construct a multifunctional potential well‐type Bi 2 Te 3 /TiO 2 topological insulator (TI) heterojunction with electric dipole domain to elucidate the synergistic mechanism, which facilitates rapid mass transport, strengthens polysulfide capture ability and accelerates polysulfide conversion. Therefore, the Li−S battery with Bi 2 Te 3 /TiO 2 TI heterojunction modified separator achieves high utilization of sulfur cathode, delivering a high reversible specific capacity of 1375 mAh g −1 at 0.2 C and long cycling capability with a negligible capacity decay of 0.022 % per cycle over 1000 cycles at 1 C. Even with the high sulfur loading of 13.2 mg cm −2 and low E/S ratio of 3.8 μL mg −1 , a high area capacity of 11.2 mAh cm −2 and acceptable cycling stability can be obtained. This work provides guidance for designing high‐efficiency TI heterojunctions to promote the practical application of Li−S batteries.